Welcome to Rapunzel's Delight

Home
About Rapunzel's Delight
Braids, Updos & Styles
Hair Facts
Hair Care
Guestbook
Funny Stuff
Email & Contact Info
Site's Junk Folder

External Links

Long Hair Community Forum

Dr. Rath Research

Feeds & Things

You Tube
Flickr Feeds


Hair Forums
Health Sites

Hair News
Health News
Chemical News
Temp Archive

Rapunzel's Store

Under Construction !!!

Health Books

Magazines


Supplements

Herbal Supp

Super Foods

Wheatgrass

Omega Oils

Bulk Herbs


Bath Soaps

Water Filters


Store Info Page


Combs

Hair Brushes

Hair Dryers


Shampoos

Conditioners

Styling Aids

Camellia Oil


Vision Workout

Lung Exercisers

Trampolines

Guests

Sam's Care for Floor Length Hair
Avoid Toxins In Life by Vicky Zhou
Colon Cleansing by Angela Chang
The Thompson Collection
Thompson Photography
Long Hair Lynn

Health Topics

Dietary Supplements
Free Radicals & Antioxidants
Natural vs. Allopathic
Acid Alkaline Balance
Noxious Shampoos
Lymphatic System
Meats vs. Veggies
Toxic Chemicals
Digestive Care
Pure Water
Parasites
Cleanses

Home Recipes

Conversion Tables
Beneficial Herbs & Oils
Natural Cleaners
Conditioners
Shampoos
Rinses

Links related to....

Healthy Living
Research
Hair

Image Galleries

Hi-Res  Images
House of David
Sutherland Sisters
Stan Shuttleworth
Waist to Ankles 5
Waist to Ankles 4
Waist to Ankles 3
Waist to Ankles 2
Waist to Ankles 1
Ankles & Beyond
Advertisements
Unusual
Updos
Art

Vintage Potpourri

Miss Jackie Walls
Newspaper Clippings 1
Newspaper Clippings 2
Palnora Hair Grower
Inventions & Patents
Scientific Care of the Hair ~ 1921
The Care of the Hair ~ 1922
The Coiffure Lesson ~ 1910
Hair Troubles ~ 1885
Hair Culture ~ 1901
Hair Care ~ 1890
Evidence ~ 1906
Kotalko Soap

Stories

Lady Godiva
Chief Long Hair
Rapunzel

Legal Stuff

Credits & References
Privacy Statement
Copyright Info
Disclaimer

 

Photographer A.L. Henderson of London Bridge

Rapunzel's

All things long and beautiful hair
for friends, health, & support.

Delight

Healthy Hair Concept

Store Info Page

Search Website

Noxious Shampoos

Revised Monday December 17, 2007

Toxic Chemicals in Shampoos

Just when you thought it was safe to shampoo... think again !!!  Go get your shampoo bottle and look at the listed ingredients.  You might find the following chemicals:

Chemical

An irritant affecting...

Used as...

Produces cancer?

Other info

  • Skin

  • Eyes

  • Respiratory Passages

  • Glass cleaners

  • All-purpose cleaners

  • Disinfectants

No evidence

Vapors extremely toxic

Ammonium Lauryl Sulfate

 

(ALS)

  • Skin

  • Eyes

  • May have drying effect on the skin.

     

Olefin Sulfonate

  • Eye (Ocular irritation)

  • Toilet bowel cleaner

  • Car wax & wash

No evidence

jump to chemical data sheet

Cocamidopropyl Betaine

  • Skin

No evidence

Contact, shampoo, and eyelid dermatitis...
Re: TOXNET

Sodium Lauryl (Laureth) Sulfate

 

(SLS)

  • Skin

  • Foaming agent

  • Engine cleaners

  • Garage floor cleaners

YES, when combined with other substances. (see Nitrate Absorption)

Systemic: penetrating into the eyes, heart, liver, and brain

MSDS

Sodium Coco Sulfate

       

Propylene Glycol

  • Skin

  • Antifreeze

  • Brake and Hydraulic Fluids

No evidence

Contact dermatitis and allergies, kidney and liver damage

MSDS

This table is a quick reference and index guide for this page.  Chemicals listed are discussed in further detail and linked to the appropriate bookmarks within this page.  Material Safety Data Sheet (MSDS) link is also provided for each chemical, if any.
P.S.  This table will grow over a period of time- I guarantee it  -Webmaster

Main References

Toxic Chemicals in Shampoos?

Just briefly, the following is a general description of toxic chemicals found in shampoos:

  • PEG  PEG compounds - Any substance abbreviated as "PEG" (Polyethylene Glycol) or with polyethylene in its chemical makeup is probably contaminated with 1,4-Dioxane.  1,4-Dioxane produces cancer !!!
  • FRAGRANCE Fragrances are the leading cause of allergies.  Artificial fragrances can be made up of more than 800 individual ingredients, some which are very toxic, and others that have never been adequately tested.
  • PROPYLENE GLYCOL  This ingredient causes allergic problems for some people.  Also, this stuff is antifreeze !!!
  • SODIUM LAURETH SULFATE
    SODIUM LAURYL SULFATE (SLS)
    SODIUM LAURYL ETHER SULFATE (SLES) 
    The Laureth compounds are often contaminated with carcinogen 1,4-Dioxane.  (Carcinogen means cancer causing.)  Stay away from any ingredient that has the "eth" in its name, it might be contaminated with 1,4-Dioxane.  Also, Sodium Lauryl Sulfate is a systemic toxin and can cause eye problems. (Systemic means
    "affecting an entire system or body as a whole") Further, SLS corrodes the hair follicle and makes hair grow slower !!! 
  • DICTHANOLAMINE  (DEA)   DEA has been shown to be carcinogenic in experimental studies.
  • triethanolamine (TEA) 
  • FORMALDEHYDE  This chemical is used as a  preservative in many shampoos. However, Shampoo manufactures are not required to list 'formaldehyde' as an ingredient.  Rather, it is label as 'quaternium-15"

Why do they put this stuff in shampoos?  Because it's cheap... cheap... cheap !!!   ...plus, because of all of that thick lather and smells, it looks like you're really getting your money's worth !!!

Sodium Lauryl (Laureth) Sulfate ~  "SLS"

jump to chemical data sheet


Intelligencer, The
Monday, December 26, 1988 Doylestown, Pennsylvania

Sodium Lauryl Sulfate or Sodium Laureth Sulfate (SLS) is a  foaming boaster (anionic surfactant) and a wetting agent, a common detergent found in shampoos.  According to Journal of the American College of Toxicology, in the report on the safety of Sodium Lauryl Sulfate, notes that this ingredient has a "degenerative effect on the cell membranes because of its protein denaturing properties."  The journal adds, "high levels of skin penetration may occur at even low use concentration."  Studies indicate eye health is also a concern.  Sodium Lauryl Sulfate keeps young eyes from developing properly by possibly denaturing the proteins and not allowing for proper structural formation.  (Denature means "to change the nature or natural qualities of")

SLS comes from coconut oil (via commercial processing) and helps make substances foam or lather.  It's a detergent.  The same ingredient found in detergent soaps such as garage floor cleaners and engine degreasers.  According to U.S. government, Material Safety Data Sheet (MSDS), Exposure to SLS can lead to a burning sensation, coughing, wheezing, laryngitis, headache, nausea, and vomiting,  SLS can damage vital internal organs and wipe-out your immune system, and can result in blindness, such as cataract formation.  See Wall Street Journal (January 11, 1988)

If that doesn't sound bad, listen to this !!!  By penetrating (via absorption) into the skin, SLS has been blamed for corroding the hair follicle causing premature hair loss.  And... if your hair isn't falling out by now, this stuff (via corroding effect on the follicle) causes your hair to grow slower !!!

SLS is found in 90% of commercial shampoos and conditioners.  It's even found in our toothpaste.  Of all places... toothpaste!  Why would they put this stuff in toothpaste???


Gettysburg Times, The
Tuesday, July 18, 1995 Gettysburg, Pennsylvania

 


Gleaner, The
Wednesday, June 17, 1998 Kingston, Kingston

Okay, I got it! They figure our eating habits are sooooo bad they equate our foods with greasy engines and dirty garage floors.  They figure we need that industrial strength SLS stuff to make our teeth feel really-really clean.  Makes sense to me :-)


SLS Overview

A study done at the Medical College of Georgia has shown:

  • Shampoos (with SLS) could retard healing and keeps children’s eyes from developing properly, children under six are especially vulnerable to improper eye development (Summary of Report of Research to Prevent Blindness, Inc. conference)

  • SLS can cause cataracts in adults and delays the healing of wounds in the surface of the cornea

  • SLS builds up in the heart, liver, lungs and brain and can cause major problems in these areas

  • SLS causes skin to flake and to separate and causes substantial roughness on the skin

  • SLS causes dysfunction of the biological systems of the skin

  • SLS is such a caustic cleanser that it actually corrodes the hair follicle and impairs its ability to grow hair.

  • SLS is routinely used in clinical studies to deliberately irritate the skin so that the effects of other substances can be tested.

(I don't know if both reports came from the same source or individual studies.  I will find out!  -webmaster)

A report from the Journal of the American College of Toxicology; Vol. 2, No. 7, 1983 states:

  • SLS is routinely used in clinical studies to irritate skin tissue. 

  • SLS corrodes hair follicle and impairs ability to grow hair.

  • Carcinogenic Nitrates can form when SLS interacts with other nitrogen bearing ingredients.

  • SLS enters and maintains residual levels in the heart, liver, lungs and brain from skin contact. (Shampoos?)

  • SLS denatures protein, impairs proper structural formation of young eyes - damage permanent.

  • SLS can damage the immune system; cause separation of skin layers and cause inflammation to the skin.


Carcinogenic 1,4-Dioxane

The U.S. Food and Drug Administration (FDA) has conducted surveys of cosmetic raw materials and finished products for the presence of 1,4-Dioxane since 1979.  According to the 2001 report from the FDA own researchers, "1,4-Dioxane was found at levels up to 279 ppm (parts per million) in cosmetic finished products."  The researchers add, Levels of 1,4-Dioxane in excess of 85 ppm in children's shampoos indicate that continued monitoring of raw materials and finished products is warranted."

According to the National Toxicology Program studies, the chemical  1,4-Dioxane has induced cancer in both sexes of rats and both sexes of mice.

According to the Consumer Product Safety Commission, the presence of 1,4-Dioxane, even a trace contaminant, is cause for concern.


Carcinogenic DEA-based compounds

According to a 1998 report from the federal National Toxicology Program, two DEA-based compounds, Cocamide DEA and Lauramide DEA, have been demonstrated to be cancer causing in at least one species of animal.  (DEA is also known as Diethanolamine)


Estrogenic preservative alkyl-hydroxy-benzoate

Alkyl-hydroxy-benzoate,  Alkyl-hydroxy-paraben, and Alpha-hydroxy-benzonate, Ethyl-paraben are used as a preservative in shampoos.  The following prefixes are related to this preservative:

  • methyl-
  • ethyl-
  • propyl-
  • butyl-

These on the left are known as
"Parabens"

They inhibit microbial growth and extend product's shelf life.

These compounds are allergenic and estrogenic.  (Estrogenic means "relating to or caused by estrogen.")  Researchers concluded that, "Given their use in a wide range of commercially available topical preparations, it is suggested that the safety in use of these chemicals should be reassessed..."

 

Material Data Safety Sheet (MSDS)

According to United States Code of Federal Regulations (CFR) at 29 CFR part 1910.1200, a Material Safety Data Sheet (MSDS) is a document obtained or developed for each hazardous chemical produced, imported or used by chemical manufacturers or importers.  The MSDS informs workers and emergency personnel with the proper procedures for handling or working with a particular substance.


Propylene Glycol ~ Antifreeze?

jump to chemical data sheet

 

Propylene Glycol is another chemical commonly found in shampoos.  Now get this... it's used in antifreeze !!!   In fact, it's used as antifreeze !!!  Yea, antifreeze...  the same stuff used in your car's coolant.  The same stuff used in airplane's deicing fluids !!!  It's also used in...

  • Brake and Hydraulic Fluid

  • Paint and Coatings

  • Floor Wax

  • Portable Water Systems

  • Swimming Pools

  • Liquid Laundry Detergents

  • Pet Food and Tobacco

Propylene Glycol is a clear odorless water-retaining liquid produced by the hydration of propylene oxide.


Market use break-down for Propylene Glycol

 
Unsaturated Polyester Resins 38%
Food, Pharmaceuticals, Cosmetics 17%
Deicing/Functional Fluids 13%
Liquid Landry Detergents 9%
Pet Foods 5%
Tobacco 4%
Paint and Coatings 4%
Other 10%

Page 36, Chemical Business,

November 1992

 

A surfactant is a "substance capable of reducing the surface tension of a liquid in which it is dissolved."  In other words- it's a detergent.

Types of Surfactants (Comparative surfactant toxicity followed the general order 1-4):

  1. Cationic  a positively charged (ionized) surfactant

  2. Anionic  a negatively charged (ionized) surfactant

  3. Nonoinic  no charge to the  surfactant

  4. Amphoteric a negatively and positively charged surfactant.

Source: TOXNET

 


Nitrate Absorption

The nitrate absorption occurs when SLS becomes contaminated with NDELA (N-nitrosodiethanolamine) during processing.  This contamination comes about as a result of SLS coming into contact with any number of chemicals including Triethanolamine (TEA), which is a commonly used ingredient in shampoos.  In other words, for example:

SLS + TEA= NDELA

NDELA is a nitrosamine and a recognized carcinogen !!!

NITROSATING AGENTS

  • 2-bromo-2-tropropane- 1,3-diol

  • Cocoyl sarcosine

  • Diethanolamine (DEA) plus any chemical listed

  • Imidazolidinyl urea

  • Formaldehyde

  • Hydrolyzed animal protein

  • Lauryl sarcosine

  • Monethanolamine (MEA)

  • Monethanolamine (MEA) plus any chemical listed

  • Quatemium-7, 15, 31, 60, etc.

  • Sodium lauryl (or laureth) sulfate

  • Sodium methyl cocoyl taurate

  • Triethanolamine (TEA) plus any chemical listed

NITROSAMINES - Shampooing the hair with a product contaminated with this substance can lead to its absorption into the body at levels much higher than eating nitrite-contaminated foods.  Avoid these chemicals.

Reference: Wall Street Journal, Jan. 11, 1988

 


Artificial Fragrances

Most fragrances are synthesized from petroleum products.  They are artificial.   They make you think your smelling something wonderful.  When in fact, you are smelling a combination of synthetic, volatile chemicals or Volatile Organic Compounds (VOC). These chemicals are "volatile" because they are actually releasing fumes.

Fragrances (identified as 'Parfum' in the EU; 'Fragrance' in the USA) are the leading cause of allergies.  Artificial fragrances can be made up of more than 600-800 individual ingredients, or any combination thereof, some which are very toxic, and others have never been adequately tested.  The fragrance industry is self-regulated.  Which means, tests do not reflect any damaging results.

Reference Links


Books

cover
Cosmetics Unmasked
cover
Beauty to Die for- The Cosmetic Consequence
cover
Dying to Look Good
Cosmetics Unmasked Homepage

 


Bad stuff in skin care products...

 


Gettysburg Times
Saturday, June 11, 2005 Gettysburg, Pennsylvania

  • Stay away from solvents !!!  Solvents such as Isopropyl alcohol, Propylene glycol, and Butylene glycol will penetrate your skin and breakdown the skin's intercellular mortar, making your skin sag.

  • Stay away from synthetic fragrances !!!   Synthetic fragrances can irritate the skin and strip away it's natural protection.  Synthetic fragrances have been known to cause headaches, dizziness, rashes, asthrnatic complications, etc..

  • Stay away from synthetic color pigments !!!  Synthetic pigments can often be carcinogenic (cancer causing.)

  • Stay away from preservatives !!!  Preservatives such as DMD, Hydantion, Imidaxolidinyl urea, and Phenoxyetyhanol, will release trace amounts of formaldehyde into the skin, resulting in a toxic effect at cellular level.

  • Stay away from talc powder !!!  Talc powder can increase the risk of a certain type of ovarian cancer.  Use corn starch in place of talc powder.

Chemicals, such as these, can soak into the skin and accumulate over time, eventually causing health problems !!!

 


Source Documents

"Bioassay of 1,4-Dioxane for possible carcinogenicity (CAS No. 123-91-1)." National Toxicology Program, TR-80.

Bouillon, C. "Shampoos and hair conditioners." Clinics in Dermatology, 1988; 6(3): 83-92.

Conry, T. Consumer's Guide to Cosmetics. Garden City, NY: Ancor Press / Doubleday, 1980, p. 74.

"Final report on the safety assessment of Sodium Lauryl Sulfate." Journal of the American College of Toxicology; 1983; 2(7).

Sixth Annual Report on Carcinogens, 1991. Summary. U.S. Department of Health and Human Services, Public Health Service. National Institute of Environmental Health Sciences, Research Triangle Park, NC, 1991, pp. 192-195.


See Good News For Kids Who Hate Baths, Lab Notes by Jerry E. Bishop, Wall Street Journal (January 11, 1988)


"Sodium Lauryl Sulfate ammonium lauryl sulfate."1996 CIR Compendium. Washington, D.C.: Cosmetic Ingredient Review, 1996, pp. 134-135.

"Toxicology and carcinogenesis studies of coconut oil acid diethanolamine condensate (CAS NO. 68603-42-9) in F344/N rats and B6C3F1 mice (dermal studies)." National Toxicology Program, TR-479.

"Toxicology and carcinogenesis studies of lauric acid diethanolamine condensate (CAS NO. 120-40-1) in F344/N rats and B6C3F1 mice (dermal studies)." National Toxicology Program, TR-480.


Sodium Lauryl Sulfate (SLS) and Ammonium Lauryl Sulfate

Published in the Journal of the American College of Toxicology, Volume 2, Number 7, pp. 127-181, 1983.


Sodium Laureth Sulfate, Sodium Lauryl Sulfate 

Published in the Journal of the American College of Toxicology, Volume 2, Number 5, pp. 1-34, 1983.


Journal of American Toxicology, Vol 2, #7, 1983, Mary Ann Leibert Inc., Publishers


 

Appendix A    Chemical Data Sheets

top of page

Ammonium Chloride    NH4Cl

MSDS

Synonyms (Alternative names commonly used for the chemical)

  • Amchlor
  • Ammoneric
  • Ammonium muriate
  • Darammon
  • Sal ammonia
  • Sal ammoniac
  • Salammoniate
  • Salmiac

Reference: CHEMINFO: Ammonium chloride

Uses

  • as an electrolyte in dry-cell batteries
  • to make quarrying explosives
  • a component of soldering flux
  • in zinc and tin plating
  • for electrolytic refining of zinc
  • as a hardener for formaldehyde-based adhesives
  • as a flame suppressant
  • in etching solutions
  • as a mordant in dyeing and printing;
  • as a fertilizer
  • in the manufacture of ammonium compounds
  • as a rapid fixer additive in photography
  • in freezing mixtures;
  • for cleaning soldering irons
  • in pharmaceuticals and veterinary medicine
  • in washing powders
  • for snow treatment
  • to manufacture dyes
  • in tanning; in cement for iron pipes and in bakery products

Reference: CHEMINFO: Ammonium chloride

Hazards

  • Fumes are toxic by inhalation.
  • Inhalation or ingestion can cause nausea, vomiting and acidosis.

Reference: Ammonium Chloride

Toxicity

  • Harmful if inhaled or ingested.

Reference: Ammonium Chloride

Appendix A    Chemical Data Sheets continued...

top of page

Cocamidopropyl Betaine   C19H38N2O3

 

Synonyms (Alternative names commonly used for the chemical)

  • 1-Propanaminium
  • 3-amino-N-(carboxymethyl)-N,N-dimethyl-
  • N-coco acyl derivs.
  • inner salts
  • Amphotensid B4 F
  • Cocamidopropyl betaine
  • Dehyton+so PK
  • Incronam 30
  • Rewoteric+so AM B-13
  • Schercotaine CAB
  • Tego+so -Betaine C
  • Tego+so -Betaine E
  • Tego+so -Betaine L-7

Reference: cocamidopropyl betaine chemical information

Uses

  • Thickener when used with anionic agents
  • Amphoteric surfactants

Reference: Safety (MSDS) data for cocamidopropyl betaine

Irritant/Dermatitis:

  • Aallergic contact dermatitis from shampoos containing Cocamidopropyl betaine

  • SHAMPOO DERMATITIS DUE TO COCAMIDOPROPYL BETAINE

  • Cocamidopropyl betaine (CAPB) is a skin irritant in man and an eye irritant in rabbits.

Reference: TOXNET  /search for Cocamidopropyl Betaine

 

Appendix A    Chemical Data Sheets continued...

top of page

Sodium Lauryl (Laureth) Sulfate ~  (SLS)   
structural  formula:  CH3-(CH2)11-O-SO3-Na+

MSDS

Synonyms (Alternative names commonly used for the chemical)

  • Ethoxylated sodium

  • laureth sulfate; ethoxylated sodium

  • lauryl ethyl sulfate; poly(oxy-1, 2-

  • ethanediyl)-sulfo-(dodecyloxy)-,

  • sodium salt

Reference: Chemistry and Fate;

  • Sodium dodecyl sulfate

  • SDS

  • Sulfuric acid, monododecyl ester, sodium salt

  • Lauryl sodium sulfate

  • Sodium N-dodecyl sulfate

  • Lauryl sulfate sodium salt

Reference:  ecis-sls abstract courtesy of the Australian government

UsesThe major uses of SLS listed the Hazardous Substances Data Base  HSDB are:

  • a surface-active agent for emulsion polymerisation, in metal processing, detergents and shampoo;

  • emulsifying, foaming, wetting, dispersing agent in creams, lotion and medical preparations;

  • foaming, wetting, and dispersing agent in toothpaste, and emulsifier, whipping agent and surfactant in foods.

Some specific examples of SLS use reported are:

  • in the preparation of blood samples for red blood cell counts,

  • the electrophoretic separation and molecular weight estimation of proteins,

  • the preparation of sample for dietary fibre content,

  • the characterisation of quaternary ammonium compounds,

  • the electroplating industry (nickel and zinc), and the formulation of injection-moulded explosives.

SLS is also reportedly used as a

  • cleansing agent in cosmetics;

  • a whipping aid in dried egg products;

  • food additive (emulsifier and thickener);

  • emulsifier, wetting agent and adjuvant in insecticides;

  • emulsifier and penetrant in varnish and paint remover;

  • anti-foaming agent in solid rocket propellants;

  • model surfactant and reference toxicant in aquatic and mammalian toxicological testing.

Reference:  ecis-sls abstract courtesy of the Australian government

Hazards

  • Data support the findings on SLS that the chemical is of moderate acute oral toxicity, and irritant to the skin and eye in both animals and humans.

Reference:  ecis-sls abstract courtesy of the Australian government

Toxicity

  • Acute toxicity data in the rat show that SLS is harmful by the oral route.

  • SLS is a skin and eye irritant in rabbits, and skin irritation has been observed in clinical studies in humans.

Reference:  ecis-sls abstract courtesy of the Australian government

Appendix A    Chemical Data Sheets continued...

top of page

Propylene Glycol   C3H8O2

MSDS

Synonyms (Alternative names commonly used for the chemical)

  • 1,2-DIHYDROXYPROPANE

  • 2-HYDROXYPROPANOL METHYLETHYLENE GLYCOL

  • METHYLETHYL GLYCOL

  • METHYL GLYCOL

  • MONOPROPYLENE GLYCOL

  • PG 12

  • PROPANE-1,2-DIOL

  • 2,3-PROPANEDIOL

  • ALPHA-PROPYLENE GLYCOL

  • 1,2-PROPYLENE GLYCOL

  • SIRLENE

  • TRIMETHYL GLYCOL

Reference: Household Products Database

Uses:

  • COMPONENT OF CELLOPHANE

  • Used as a humectant in foods, such as shredded coconut, in tobacco, and in pet food

  • Used as an emollient in cosmetic and pharmaceutical creams

  • Solvent in food colors and flavors

  • Used in industry as a lubricant or heat-transfer fluid where leakage might lead to food contact (eg. coolants for dairy refrigeration equipment)

  • Aqueous solutions of propylene glycol containing a corrosion inhibitor are used for low-temperature protection of fresh-water plumbing in recreational vehicles and boats

  • Used as a raw material for plasticizers, such as polypropylene adipate, the linear polyester of propylene glycol and adipic acid

  • Additive to latex paint to provide freeze-thaw stability

  • Used as a humectant in dentifrices

  • Used in a gas-phase reaction with ethylenediamine to produce 2-methylpiperazine

  • 1,2-propylene glycol is reductively aminated to produce 1,2-propylene diamine

  • Vapors of propylene glycol can protect animals against airborne bacteria and influenza virus under controlled conditions of temperature and humidity

  • Serves as a base in aircraft deicing fluids

  • Propylene glycol is used in the production of hydroxylated polyesters

  • Propylene glycol is heated with trimellitic anhydride and phthalic anhydride with catalytic amounts of sulfuric acid to produce a polyester-type fluorescent resin matrix

  • Propylene glycol reacts with propylene oxide to form a homopolymer used in the preparation of polyether polyols

  • Used as an antifreeze in breweries and establishments, solvent for pharmaceuticals, substitute for ethylene glycol and glycerol, inhibitor of fermentation and mold growth, emulsifier in foods

Reference: toxnet @HSDB

Health Hazards Acute & Chronic:

  • SKIN: MILD IRRITATION, DERMATITIS, ERYTHEMATOUS EDEMATOUS PLAQUES, CNS DEPRESSION. INGESTION: 60 ML WILL CAUSE REVERSIBLE CNS DEPRESSION. POISONING MAY AFFECT THE CNS & KIDNEYS.

Reference: U.S. Department of Defense MSDS at Cornel University

Appendix A    Chemical Data Sheets continued...

top of page

Sodium C14-C16 olefin sulfonate

 

Synonyms (Alternative names commonly used for the chemical)

Following are Sodium alpha-Olefin Sulfonates:

  • Sodium C14-16 Olefin Sulfonate

  • Sodium C12-14 Olefin Sulfonate

  • Sodium C14-18 Olefin Sulfonate

  • Sodium C16-18 Olefin Sulfonate

    (Source: @TOXLINE Special)


  • Sodium C14-C16 olefin sulfonate

  • Sulfonic acids

  • C16-C18-alkane

  • sodium salts

  • Sulfonic acids

  • C14-16-alkane hydroxy and C14-16-alkene, sodium salts

Source: Household Products Database

Uses:

  • Car wax & wash

  • Tank toilet bowel cleaner

  • Used in cosmetics as surfactant-cleansing agents. The highest concentration reportedly is 16% in shampoos and bath and shower products.

Ocular means: "Having to do with the eye."

Please note (in the lower left column) that concentrations above 10% produced mild ocular irritation.  -Webmaster

Source: Household Products Database

Irritant:

  • Concentrations above 10% produced moderate ocular irritation and a concentration of 5% produced mild ocular irritation in rats.

Source: INTERNATIONAL JOURNAL OF TOXICOLOGY; 17 (SUPPL. 5). 1998. 39-65. Full Display - Frameset @TOXLINE Special

Appendix A    Chemical Data Sheets continued...

top of page

   

Synonyms (Alternative names commonly used for the chemical)

  •  

Reference:

Uses:

  •  

Reference:

Health Hazards Acute & Chronic:

  •  

Reference:

 

 

 

Appendix B    Example of Shampoo's Ingredients

top of page

TRESemme European Shampoo, Vitamin E Moisture Rich

Ingredients: Water, Sodium Lauryl Sulfate, Cocamidopropyl Betaine, Polyquaternium-39, Quaternium-22, Polyquaternium-10, Panthenol, Tocopheryl Acetate, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Prunus Amygdalus Dulcis Fruit Extract (Sweet Almond), Corylus Americana Leaf Extract (Hazel), Helianthus Annuus Extract (Sunflower), Propylene Glycol, Camellia Sinensis Leaf Extract, Epilobium Angustifolium Extract, Foeniculum Vulgare Fruit Extract (Fennel), Butylene Glycol, Citric Acid, Ammonium Chloride, DMDM Hydantoin, Tetrasodium EDTA, Fragrance


Australian Organics Body Maximising Shampoo for Fine, Limp + Oily Hair

Ingredients: Aqueous Extracts of Chamomile, Lime blossom and Birch (certified organic), TEA Lauryl Sulfate (Coconut Derived), Cocoamidopropyl Betaine (Coconut Derived), PEG 60 Almond Glycerides, CDE, Hydrolyzed Wheat Protein, Soya Protein and Wheat Amino Acids, PEG 35 Castor Oil / Polysorbate 20 / Horsechesnut Extract / Retinal A Palmitate (Vitamin A) / Tocopherol (Vitamin E) / PABA / Inositol (Vitamin B) / Calcium Pantothenate (Vitamin B5) / Linolic Acid (Vitamin F) / Biotin (Vitamin H), Citric Acid, Disodium EDTA, Sea Salt, Sodium Benzoate Chloracetamide, Geranium Essential Oil, Lavender Spike Essential Oil, Lemon Essential Oil, B-Carotene / Paprika

ABBA Complete, Shampoo For All Hair Types


Ingredients: Botanical Infusion of Prunus Virginiana (Cherry Bark), Lavandula Angustifolia (Lavender), Citrus Aurantium Bergamia (Bergamot); Ammonium Lauryl Sulfate, Cocamidopropyl Betaine, Polypropoxyethoxy Cocamide (Coconut), Hydroxypropyl Methylcellulose, Lupin Amino Acids (150mw), Hydrolyzed Soy Protein (1000mw), Hydrolyzed Wheat Protein (2000mw), Hydrolyzed Wheat Starch (Plant), Citric Acid (Fruit), Glycol Stearate (Coconut), Methylparaben (Food Grade Preservative), Sodium Chloride, Methylcholoroisothiazolinone, Methylisothiazolinone (Preservative), ABBA's Aromatherapy Fragrance


Avalon Organics Shampoo, Thickening, Biotin B-Complex

Ingredients:  Certified Organic Lavender Hydrosol (Lavandula Officinalis) and Certified Organic Saw Palmetto (Sarenoa Serrulata) and Aloe Barbadensis, Sodium Cocoyl Glutamate, Disodium Cocoamphodiacetate and Cocamidopropyl Betaine (from Coconut), Certified Organic Wheat Protein (Triticum Aestivum), Biotin and Niacin (Vitamin B Complex), Certified Organic Jojoba Oil (Simmondsia Chinensis), Panthenol (Pro-Vitamin B5), Vegetable Glycerin, Zinc Gluconate, Citric Acid, Methyl/Propylparabens, Grapefruit Seed Extract (Citrus Grandis) and pure essential oils.

Alberto VO5 Shampoo for Normal Hair


Ingredients: Water, Sodium Lauryl Sulfate, Cocamidopropyl Betaine, Ammonium Chloride, Tocopheryl Acetate (Vitamin E), Panthenol (Pro-Vitamin B5), Retinyl Palmitate (Vitamin A), Ascorbic Acid (Vitamin C), Octoxynol-9, Ergocalciferol (Vitamin D), Tetrasodium EDTA, Sodium Laureth Sulfate, DMDM Hydantoin, Fragrance, Citric Acid, Yellow 6

 


Nature's Gate The Original Herbal Hair Shampoo

Ingredients:  Water Extracts of Nettles, Sage, Chamomile, Kusambi Bark, Lavender, Yarrow, Rosemary, Wild Cherry Bark and Thyme, Sodium Laureth Sulfate, Cocamidopropyl Betaine, Cocamide DEA, Citric Acid, Methyl & Propyl Parabens, Chlorophyllin, Fragrance Oils


Nature's Gate Organics Shampoo, Soy Fragrance-Free


Ingredients:  Certified Organic *Lemon Verbena Hydrosol, Certified Organic *Lavender Hydrosol, Infusion of Certified Organic Marshmallow*, Horsetail**, Cucumber**, Witch Hazel**, Chamomile**, Echinacea**, Olefin Sulfonate, Cocamidopropyl Betaine, Sodium Myreth Sulfate, Cocamide MEA, Methyl Glucose Dioleate, Hydrolyzed Soy Protein (Non-GMO), Certified Organic Aloe Vera**, Certified Organic Yucca Extract, Panthenol (B-5), Hydrolyzed Wheat Protein, Hydrolized Wheat Starch, Soyamidopropalkonium Chloride (Soy NON GMO), Disodium EDTA, Grafruit Seed Extract

Appendix B    Shampoo's Ingredients

top of page

SANI-FRESH INTERNATIONAL
EUROBATH HAIR & BODY SHAMPOO

 =======================================================
Ingredients
=======================================================
Cas: 9004-82-4
RTECS #: WB7499000
Name: SODIUM LAURYL ETHER SULFATE
% Wt: 20-40
------------------------------
Cas: 61789-40-0
Name: COCAMIDOPROPYL BETAINE *97-2*
% Wt: 1-10
------------------------------
Cas: 7647-14-5
RTECS #: VZ4725000
Name: SODIUM CHLORIDE       *97-2*
% Wt: <5
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: MAY CAUSE RESPIRATORY IRRITATION. SKIN: MAY
  CAUSE MILD IRRITATION. EYES: MAY CAUSE BURNING & IRRITATION.

Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, BURNS, NAUSEA.
First Aid: INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/LARGE AMOUNTS OF
  WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL
  ATTENTION IN ALL CASES.

Dietary Supplements ] Free Radicals & Antioxidants ] Natural vs. Allopathic ] Acid Alkaline Balance ] [ Noxious Shampoos ] Lymphatic System ] Meats vs. Veggies ] Toxic Chemicals ] Digestive Care ] Pure Water ] Parasites ] Cleanses ]